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The Lalibela rock-hewn churches are one of the most important religious pilgrimage sites in Ethiopia. These churches are carved from the scoriaceous basalt rock substrate, which has been exposed to attack by biological agents with significant loss of surface material. Particularly, the widespread growth of lichens and other microorganisms on the carved surfaces of the churches has proven to represent a substantial threat for the preservation of the site. In this study, laboratory tests have been conducted to assess the feasibility of using laser technology as an efficient cleaning method of biological patina from polymineralic stone substrates. Multi-analytical techniques were applied for the characterization of the stone samples collected from two of the Lalibela churches: Bete Giyorgis and Bete Amanuel. Stone samples artificially inoculated with bacteria, yeast, fungi isolates, and lichen-encrusted samples were laser cleaned using UV and IR laser wavelengths. The high content of Fe and Ti oxides and the high porosity have made the stone surfaces easily susceptible to low-energy laser treatment. Results indicate that laser cleaning can be applied to polymineralic lithotypes and UV irradiation can successfully remove lichen colonies. Further studies need to be conducted to optimize the laser procedure in polymineralic, high porosity stones.  相似文献   
34.
For the 1993–2009 period, we analyzed the relationship between almond yield and three climatic variables (mean annual temperature, soil water reserve, and precipitation), and four bioclimatic variables (annual ombrothermic index, water deficit, simple continentality index, and compensated thermicity index), for one major Hebron crop (soft and hard almonds). Moreover, we obtained data almond production from the Palestinian Central Bureau of Statistics, while the climate data from the Palestinian meteorological station during the study period from 1993 to 2009, and analysis is it by using bioclimatic classification of the Earth of Salvador Rivas-Martinez to study the relationship between the almond yield and climate and bioclimate factors (variables). The climatic and bioclimate variables of greatest importance to almond were used to develop regressions analysis relating yield to climatic conditions. Hebron was positively affected by annual ombrothermic index, simple continentality index, precipitation, water soil reserve, and mean annual temperature, but negatively affected by water deficit, with a large proportion of the variance explained by axis F1 (72.48%), F2 (22.38%), and axes F1and F2 (94. 86%). However, in order to produce a high amount of almonds and quality, it can be grown in the regions of the mesomediterranean region, with the value of annual ombrothemic index more than 3, compensated thermicity index between 220/220 to 350/350, simple continentality index between 14 and 20, and in areas where the average annual temperature is between 15 and 20 °C.  相似文献   
35.
Patellid limpets are key species on rocky shores, structuring intertidal assemblages through their grazing. Their role as prey for fish is, however, often overlooked in studies of intertidal ecosystem functioning. The shanny Lipophrys pholis is a common predator of limpets on rocky shores in Northern Europe and, in this study, we examined the characteristics of its predation on limpets based on prey size. The limpet size range that adult L. pholis (10–12.5 cm) can eat was examined in the laboratory using Patella depressa in 0.2 cm classes, varying between 0.5 cm and 3.0 cm in maximum shell length. There was a limpet size refuge above 1.8 cm, while all smaller sizes were readily consumed by the shanny. The predator attacking behaviour was also examined and found to vary with prey size. Limpets up to 0.8 cm were crushed by the jaw‐constricting force and eaten whole, whereas larger prey were prised from the substratum and the body subsequently separated from the shell. To examine whether there was a L. pholis preference for P. depressa size, a two‐stage laboratory experiment was done using two size classes defined as small (0.7–0.8 cm maximum shell length) and large (1.5–1.6 cm maximum shell length). In the first stage, the predator was given each limpet size class separately. In the second stage, the fish was given a choice between the two classes. Lipophrys pholis was shown to have a preference for the large size class (1.5–1.6 cm). The average number of limpets consumed by the shanny was examined for the duration of one high‐tide typical of the central region of Portugal (≈ 4 h). On average, approximately five limpets (up to an eight limpet maximum) were consumed. The present study shows that L. pholis has a feeding preference based on limpet size, which suggests that the limpet population structure and intra‐ and inter‐specific interactions may be influenced by the shanny predation.  相似文献   
36.
Paleoweathering in the Sergi Formation has been classified and analyzed to ascertain its origin and relationship with stratigraphic evolution. The Sergi Formation belongs to the pre-rift sequence of the Recôncavo Basin (northeastern Brazil) and comprises a complex association of eolian and fluvial sandstones and lacustrine mudstones. This formation can be subdivided into three depositional sequences bounded by regional unconformities. Four paleoweathering types, each one related to a distinct origin, have been described in the Sergi Formation: (1) textural mottling, which is distinguished by alternating rock colors as a result of the iron oxide mobilization within mineral phases that evolved under alternating oxidation (yellowish, brownish and reddish shades) and reduction (grayish or greenish hues) conditions; (2) non-textural mottling, which displays a discoloration pattern that is independent of the original rock texture; (3) carbonate concentrations, usually related to carbonate nodule formation, which display a massive internal structure that reveals their origin through continuous growth or crystallization; and (4) banded carbonates (silicified), associated with the beginning of regular surface formation due to the chemical precipitation of carbonates within lacustrine environments. Both mottling color motifs and carbonate accumulation usually represent groundwater oscillation rather than pedogenesis. Only carbonate intraclasts and banded carbonate (silicified) have their origin ascribed to pedogenesis sensu stricto, although the carbonate intraclasts do not represent soil deposits in situ, but calcretes eroded from areas close to channels, and the banded carbonates (silicified) have strong diagenetic modifications. Therefore, it is reasonable to assume that fluvial and meteoric water have controlled paleoweathering evolution as well as deposition, yet both aspects are ruled by the same mechanisms (relief, sedimentation rate and, above all, climate).  相似文献   
37.
This paper focuses on the hypothesis of stability in the mechanisms of spatial dependence that are usually employed in spatial econometric models. We propose a specification strategy for which the first step is to solve a local estimation algorithm, called the Zoom estimation. The aim of this stage is to detect problems of heterogeneity in the parameters and to identify the regimes. Then we resort to a battery of formal Lagrange Multipliers to test the assumption of stability in the processes of spatial dependence. The alternative hypothesis consists of the existence of several regimes in these parameters. A small Monte Carlo serves to confirm the behaviour of this strategy in a context of finite size samples. As an illustration, we solve an application to the case of the hypothesis of convergence for the per capita income in the European regions. Our results reveal the existence of a strong Centre-Periphery dichotomy in which instability extends to all the elements (coefficients of regression as well as parameters of spatial dependence) that intervene in a classical conditional β-convergence model.  相似文献   
38.
A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
39.
Recently, the debate surrounding the United Nations Convention in the Law of the Sea (UNCLOS) and the Exclusive Economic Zones (EEZ) has been extended to the realm of economic growth and planning. Although coastal states are making efforts to determine what resources they have in their EEZs, little is known about the exact contribution those resources are making or potentially could make to enhanced economic growth. This paper suggests an accounting framework, based on existing literature, which explicity delineates the industries that should be considered a part of the marine sector. Criteria are suggested to help determine exactly where a particular industry falls. Several methodological issues are discussed in detail.The views expressed here are those of the author and do not necessarily represent those of the United Nations.  相似文献   
40.
A comparative study of blue and green beryl crystals (from the region of Governador Valadares, Minas Gerais, Brazil) using electron paramagnetic resonance (EPR) and optical absorption (OA) spectroscopy is reported. The EPR spectra show that Fe3+ in blue beryl occupies a substitutional Al3+ site and in green beryl is localized in the structural channels between two O6 planes. On the other hand the infrared spectra show that the alkali content in the blue beryl is mostly at substitutional and/or interstitial sites and in green beryl is mostly in the structural channels. The OA spectra show two types of Fe2+. Thermal treatments above 200° C in green beryl cause the reduction of Fe3+ into Fe2+ accompanied by a change of color to blue. The blue beryl color does not change on heating. The kinetics of the thermal conversion of Fe3+ into Fe2+ is composed of two first order processes; the first one has an activation energy ΔE 1=0.30 eV and the second one has an activation energy ΔE 2=0.46 eV.  相似文献   
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